Product ID:DEMAND CS INSECTICIDE
MSDS Date:07/01/1994
FSC:6840
NIIN:01-428-6646
Status Code:A
MSDS Number: CKBGN

ZENECA INC., ZENECA PHARMACEUTICALS GROUP

1800 CONCORD PIKE
WILMINGTON, DE 19803-2902
US

Emergency Phone: 800-424-9300(CHEMTREC)/800-327-8633

Info Phone: 302-886-3000

Preparer: NOT PROVIDED.

Cage: 0A273

ZENECA INC., ZENECA PHARMACEUTICALS GROUP

WILMINGTON, DE 19803-2902 US

Telephone: 302-886-3000

Cage: 0A273

LAMBDA-CYHALOTHRIN

CAS: 91465-08-6

RTECS: GZ1227780

OSHA PEL NOT LISTED

ACGIH TLV: NOT PROVIDED.

OTHER INGREDIENTS INCLUDING INGREDIENTS 3 AND 4

OSHA PEL NOT LISTED

ACGIH TLV: NOT PROVIDED.

AROMATIC PETROELUM SOLVENT

Fraction By Weight: SEE ING 2%

OSHA PEL NOT PROVIDED.

ACGIH TLV: NOT PROVIDED.

1,2,4-TRIMETHYLBENZENE (SARA 313)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: SEE ING 2%

OSHA PEL NONE

ACGIH TLV: NOT PROVIDED.

LD50 LC50 Mixture:LD50 (ORAL, RAT) > 5,000 MG/KG
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGESTION: INGESTION CAN INDUCE SIGNS
OF CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION (E.G., DROWSINESS,
DIZZINESS, LOSS OF COORDINATION, FATIGUE). SMALL AMOUNTS OF THE
SOLVENT ASPIRATED INTO THE LUNGS DUR ING INGESTION OR VOMITING MAY
INDUCE SEVERE LUNG CONGESTION, COMA, AND DEATH. EYE CONTACT: MILDLY
IRRITATING. SKIN CONTACT: MODERATE IRRITANT AND MILD SKIN
SENSITIZER. MAY CAUSE A SKIN SENSATION CALLE D PARESTHESIA WHICH IS
DESCRIBED AS A TINGLING, ITCHING, BURNING, FLUSHING, NUMBNESS
FEELING USUALLY AROUND THE MOUTH AND EYES. INHALATION: MODERATELY
TOXIC BY INHALATION. HIGH VAPOR CONCENTRATIONS CA N CAUSE CNS
DEPRESSION, HEADACHE, NAUSEA
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INGESTION CAN INDUCE SIGNS OF CNS DEPRESSION
(E.G., DROWSINESS, DIZZINESS, LOSS OF COORDINATION, FATIGUE). SMALL
AMOUNTS OF THE SOLVENT ASPIRATED INTO THE LUNGS DURING INGESTION OR
VOMITING MAY INDUCE SEVERE LUNG CONGESTION, COMA, AND DEATH. EYE
CONTACT IS MILDLY IRRITATING. SKIN CONTACT IS MODERATELY
IRRITANTING AND MILD SENSITIZER. MAY CAUSE TINGLING, ITCHING,
BURNING, FLUSHING, NUMBNESS FEELING USUALLY AROUND THE MOUTH AND
EYES. MODERATELY TOXIC BY INHALATION. HIGH VAPOR CONCENTRATIONS CAN
CAUSE CNS DEPRESSION, HEADACHE, NAUSEA
Medical Cond Aggravated by Exposure:NOT PROVIDED.

First Aid:SKIN: WASH MATERIAL OFF THE SKIN WITH PLENTY OF SOAP AND
WATER. IF REDNESS, ITCHING/A BURNING SENSATION DEVELOPS, GET
MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR
AT LEAST 15 MI NUTES. IF REDNESS, ITCHING OR A BURNING SENSATION
DEVELOPS, HAVE EYES EXAMINED AND TREATED BY MEDICAL PERSONNEL.
INGESTION: IF VICTIM IS ALERT, RINSE MOUTH AND GIVE 1 CUP OF WATER
TO DRINK. VOMITING S HOULD ONLY BE INDUCED UNDER DIRECTION OF A
PHYSICIAN. CALL PHYSICIAN. INHALATION: REMOVE VICTIM TO FRESH AIR.
IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
LABORED, GIVE OXYGEN. CONSU LT MEDICAL PERSONNEL.

Flash Point Method:SCC
Flash Point:>100.C, 212.F
Autoignition Temp:Autoignition Temp Text:N/DATA
Lower Limits:NO DATA
Upper Limits:NO DATA
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE, HALOGENATED
AGENTS.
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE AND PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:IN A FIRE SITUATION, PRODUCT MAY SUPPORT
COMBUSTION AFTER ITS WATER CONTENT HAS BOILED OFF. HEATING WILL
GENERATE TOXIC VAPORS. FIREFIGHTERS SHOULD WEAR FULL-FACE
SELF-CONTAINED BREATHING APPARATUS AN D IMPERVIOUS PROTECTIVE
CLOTHING. IF NOT LEAKING, KEEP FIRE-EXPOSED CONTAINERS COOL WITH
WATER SPRAY TO PREVENT RUPTURE.

Spill Release Procedures:WEAR SKIN, EYE AND RESPIRATORY PROTECTION
DURING CLEANUP. KEEP OUT OF SEWERS AND DRAINS. SPREAD CLAY ON SPILL
AND SHOVEL INTO AN OPEN DRUM. COVER CONTAMINATED AREAS WITH
HOUSEHOLD DETERGENT (TIDE). US E A STIFF BRUSH AND SMALL AMOUNT OF
WATER TO FORM A SLURRY. LET IT STANDS 2-3 MINUTES. SPREAD ABSORBENT
ON SLURRY AND SHOVEL MIXTURE INTO OPEN DRUM. HANDLE LARGE SPILLS
ACCORDING TO PLAN.
Neutralizing Agent:NOT PROVIDED.

Handling and Storage Precautions:CONTAINERS SHOULD BE STORED IN A COOL,
DRY, WELL-VENTILATED AREA AWAY FROM FLAMMABLE MATERIALS AND SOURCES
OF HEAT OR FLAME. EXERCISE DUE CAUTION TO PREVENT DAMAGE TO OR
LEAKAGE FROM THE CONTAINER. DO NOT STORE NEAR FEED, FOOD, OR
WITHIN THE REACH OF CHILDREN.
Other Precautions:EMPTY CONTAINER RETAINS PRODUCT RESIDUE. OBSERVE ALL
HAZARD PRECAUTIONS. DO NOT DISTRIBUTE OR MAKE AVAILABLE, FURNISH OR
REUSE EMPTY CONTAINER EXCEPT FOR STORAGE AND SHIPMENT OF ORIGINAL
PRODUCT. REMO VE ALL PRODUCT RESIDUE FROM CONTAINER AND PUNCTURE OR
OTHERWISE DESTROY EMPTY CONTAINER BEFORE DISPO SAL

Respiratory Protection:WHEN NEEDED USE MSHA/NIOSH APPROVED RESPIRATOR
FOR PESTICIDES.
Ventilation:IF NEEDED USE LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE
CONCENTRATIONS BELOW THE TLV.
Protective Gloves:IMPERVIOUS GLOVES
Eye Protection:SAFETY GLASSES, GOGGLES/ A FACESHIELD SELECTED IN
REGARD TO EXPOSURE POTENTIAL
Other Protective Equipment:AN ADEQUATE SUPPLY OF CLEAN POTABLE WATER
SHOULD BE AVAILABLE TO ALLOW THOROUGH FLUSHING OF SKIN AND EYES IN
EVENT OF CONTACT WITH THIS PRODUCT.
Work Hygienic Practices:PREVENT SKIN AND EYE CONTACT. OBSERVE OSHA PEL
IRRITATIONS. AVOID BREATHING VAPORS OR AEROSOLS. WORKERS SHOULD
SHOWER AND CHANGE TO FRESH CLOTHING AFTER EACH SHIFT.
Supplemental Safety and Health
NOTE TO PHYSICIAN: EMESIS MAY BE INDICATED IN THE ALERT PATIENT WHO HAS
INGESTED A LARGE (INTENTIONAL) QUANTITY. LAVAGE IS INDICATED FOR
THE PATIENT WHO HAS INGESTED SUCH A LARGE DOSE. HYDROCARBON PNE
UMONITIS IS A RISK IF THIS PRODUCT IS ASPIRATED.

HCC:T5
NRC/State Lic Num:NOT PROVIDED.
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED.
Decomp Temp:Decomp Text:NOT PROVIDED.
Vapor Pres:TRACE
Vapor Density:NO DATA
Spec Gravity:1.036
pH:7.25 (1%)
Viscosity:NOT PROVIDED.
Evaporation Rate & Reference:NOT PROVIDED.
Solubility in Water:READILY DISPERSIBLE
Appearance and Odor:OFF-WHITE LIQUID WITH SLIGHT ODOR TYPICAL OF
AROMATIC PETROLEUM SOLVENT
Percent Volatiles by Volume:NO DATA
Corrosion Rate:NOT PROVIDED.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NOT PROVIDED.
Hazardous Decomposition Products:COMBUSTION PRODUCTS: CARBON DIOXIDE,
CARBON MONOXIDE, NITROGEN OXIDES, AMMONIA,TRACE AMOUNTS OF HYDROGEN
CYANIDE.

Waste Disposal Methods:THIS MATERIAL IS EXTREMELY TOXIC TO FISH. DO NOT
CONTAMINATE WATERWAYS BY CLEANING OF EQUIPMENT OR BY DISPOSAL OF
WASTE. UNTREATED EFFLUENT SHOULD NOT BE DISCHARGED WHERE IT WILL
DRAIN INTO LAKES, STR EAMS, PONDS. DISCARDED PRODUCT IS NOT
HAZARDOUS WASTE UNDER RCRA, 40 CFR 261.

Toxicological Information:LD50 INGESTION RAT (BOTH GENDERS) > 5000
MG/KG; VERY LOW TOXICITY BY INGESTION. LC50 INHALATION RAT >4.62
MG/L, 4 HOURS; MODERATELY TOXIC BY INHALATION. LD50 SKIN
ABSORPTION RAT (BOTH GENDERS) > 200 0 MG/KG; SYSTEMICALLY TOXIC
CONCENTRATIONS OF THIS PRODUCT WILL PROBABLY NOT BE ABSORBED
THROUGH HUMAN SKIN.

Ecological:THIS MATERIAL IS EXTREMELY TOXIC TO FISH.

Transport Information:NOT PROVIDED.

SARA Title III Information:CERCLA AND SARA REGULATIONS (40 CFR 355,
370, AND 372): SECTION 313 SUPPLIER NOTIFICATION. THIS PRODUCT
CONTAINS THE FOLLOWING TOXIC CHEMICAL SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TH E EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT (EPCRA) OF 1986 AND OF 40 CFR 372:
<5.0% 1,2,4-TRIMETHYLBENZENE (CAS 95-63-6).
Federal Regulatory Information:TSCA (TOXIC SUBSTANCES CONTROL ACT)
REGULATIONS, 40CFR 710: THIS PRODUCT IS A PESTICIDE AND IS EXEMPT
FROM TSCA REGULAITON. EPA: EPA REGISTRATION NO.: 10182-361
State Regulatory Information:NOT PROVIDED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.